Studies on Coordination Compounds of Some Pyrazoline-5-One Derivative
Asian Resonance(P: ISSN No. 0976-8602 RNI No.UPENG/2012/426228
VOL.-III, ISSUE-IV, October-2014 E: ISSN No. 2349 - 9443)
Abstract
Professor, Deptt. of Chemistry, BRA Bihar University, Muzaffarpur
Ranjeet Kumar Singh
Research Scholar, Deptt. of Chemistry , BRA Bihar University, Muzaffarpur.
Nidhi Srivastava
Research Scholar
Some tridentate ligands were synthesized by the reaction of ethyl 2-phenylhydrazono-3-oxobutyrate and its derivative with isoniazid by the method reported in literature. The hexacoordinated complexes of Cu(II) and Ni(II) ions with these ligands were synthesized, and characterised on the basis of their electronic, IR absorption properties and magnetic properties. The composition of the complexes were found as [ML2].The analysis shows that after mono deprotonation the ligand 1-isonicotinoyl-3-methyl-4- (phenylhydrazono)-2-pyrazoline-5-one(HL),their methyl derivative HL’ and methoxy derivative HL’’ behaved as tridentate N,N,O donor ligand. The structural studies of metal complexes revealed that each metal ion is hexacoordinated. The electronic spectral band and IR spectral bands have been interpreted.
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